@foefyre I realize that you are new to FreeNAS but you really should read the user manual from cover to cover, this will answer many of your questions. Additionally please read the forum rules with respect to what data we require to help a person out. I always approach an issue by assuming one thing only, the person on the other end knows nothing about my system, problem, or what I was doing. When I think like this I put myself it their shoes and provide as much information as possible so that I can get some help without having to be asked a lot of basic questions. Yes, I too ask for help on the forums, and not just this forum.
You might also want to read through some of the forums periodically. FreeNAS was never meant to be an out of the box application to run without some basic minimal knowledge. If you value your data you will heed my words of wisdom as it will help you avoid some pain in the future.
As for the GUI not being responsive, typically that would be a low RAM issue or a bug in the program. I wouldn't think that you would have this issue with 8GB RAM however if you do have a lot of jails/applications running eating up your RAM then your SWAP partition would be very active and that could slow down the GUI, but making it completely stop, I don't see how that could happen unless you ran out of SWAP space which is unlikely unless you made changes to the SWAP space default settings.
You also said your running FreeNAS 9.10.2 but is that 9.10.2, 9.10.2-U1, or 9.10.2-U2? If you are running 9.10.2-U2 then I'd recommend rolling back to 9.10.2-U1 and see if you still have the issues.
And as
@gpsguy has said, do not add an L2ARC. Many of us have tested this configuration and we can speak from experience, with only 16GB or 32GB RAM, you will slow your system down (measurable via benchmarks) and just add complexity to it. If you had 64GB RAM, maybe, 128GB or more then yes it would benefit depending on your usage of course.