Windows of any flavor does not fair well with mapped drives on initial startup. Because you moved your user folders that are expected to be immediately accessible on the machine, it simply doesn't know what to do when trying to locate your user folders.
What you should have done, and what you should do, is have a dataset for your user. On that dataset you would then create folders such as Pictures, Documents, Videos, etc. and then COPY your files to those new folders - do not MOVE (remap) the user folders. Now that you have verified everything copied over without errors, you can safely delete the data in your user folders on the Windows machine. On Windows you will then map a network drive for the CIFS share that points to the user's dataset. From there you can create symlinks in Windows to your folders.
http://www.howtogeek.com/howto/16226/complete-guide-to-symbolic-links-symlinks-on-windows-or-linux/ You can also make those symlinks part of your Libraries.