I replaced the disk, and after removing it from the pool I did a full zero wipe from the Storage / Disks FreeNAS menu.  
After the wipe this is the output from smartctl appears to have cleared any errors
:
Code:
ID# ATTRIBUTE_NAME          FLAG     VALUE WORST THRESH TYPE      UPDATED  WHEN_FAILED RAW_VALUE
  1 Raw_Read_Error_Rate     0x002f   200   167   051    Pre-fail  Always       -       38
  3 Spin_Up_Time            0x0027   211   182   021    Pre-fail  Always       -       8425
  4 Start_Stop_Count        0x0032   100   100   000    Old_age   Always       -       313
  5 Reallocated_Sector_Ct   0x0033   200   200   140    Pre-fail  Always       -       0
  7 Seek_Error_Rate         0x002e   200   200   000    Old_age   Always       -       0
  9 Power_On_Hours          0x0032   046   046   000    Old_age   Always       -       39912
 10 Spin_Retry_Count        0x0032   100   100   000    Old_age   Always       -       0
 11 Calibration_Retry_Count 0x0032   100   253   000    Old_age   Always       -       0
 12 Power_Cycle_Count       0x0032   100   100   000    Old_age   Always       -       96
192 Power-Off_Retract_Count 0x0032   200   200   000    Old_age   Always       -       66
193 Load_Cycle_Count        0x0032   188   188   000    Old_age   Always       -       38807
194 Temperature_Celsius     0x0022   112   096   000    Old_age   Always       -       40
196 Reallocated_Event_Count 0x0032   200   200   000    Old_age   Always       -       0
197 Current_Pending_Sector  0x0032   200   200   000    Old_age   Always       -       0
198 Offline_Uncorrectable   0x0030   100   253   000    Old_age   Offline      -       0
199 UDMA_CRC_Error_Count    0x0032   200   200   000    Old_age   Always       -       0
200 Multi_Zone_Error_Rate   0x0008   200   200   000    Old_age   Offline      -       2
 
Given the nature of the data on the drive, it is quite likely that the surface has not experienced a write since the pool was created about 5 years ago since the content of the drive is largely library material that doesn't get updated frequently if at all.  Does recorded info fade with time?
Am I correct in assuming that scrub is read only unless an error is found?  No errors = no writes during scrub.
If an error is found, then the data is reconstructed and written to another part of the disk? 
Any thoughts about this behaviour?
Now that the drive is out of the pool, I am going to run one pass of badblocks followed by a selftest to see what happens.  
If the drive is clean after that would it be safe to assume that I can be as confident of the drive as I can be of any drive of the same type with a similar number of hours?