First assumption is that your problem is the frequent disk writes. "how to do it" - second assumption is that you want to move the system dataset off your datadrives and based on the "new" GUI:
Go to System, System Dataset, and choose your preferred location on the top line System Dataset Pool. I presume you will choose "freenas-boot".
If this were my system I would only choose to do this if my boot pool was on an SSD (or even a small HDD). I would not do it if booting from a USB because of their lack of reliability.