Two examples: I have a second subnet (though not 10GHz) which is used only for replication and IPMI. As far as I know neither process need know nor care about hostnames, Netbios names, or indeed anything else happening on their hosts.
And an elegant solution recently put forward by one of the forum experts in a thread about your situation, (direct 10GHz between workstation and FreeNAS), which you ought to be able to find with a suitable search; have only one (10GHz) NIC on the workstation, on your usual subnet. Set up FreeNAS with a 1gige NIC and a 10GHz one and bridge the two so they have the same IP, also on your usual subnet. Then all transactions are unchanged IP-wise and everything should work as usual, except with a 10GHz pipe between workstation and FreeNAS. All other workstation traffic has to go through the bridge, but at very worst that is 10% of capacity, and the bridge apparently does not need much processing power. I
think the bridge works in promiscuous mode and is completely transparent to subnet traffic not directly for the FreeNAS IP, but you would have to check that. Otherwise you might have to explain routing to the workstation. If you can find the thread I think it had some useful hints on how to set up the bridge.
Edit:
https://forums.freenas.org/index.ph...0gb-10gb-1gb-setup-without-10gb-switch.25259/