I have this set up at home. My router has multiple wan interfaces. I set up the router with a DMZ, Home, and two WANs to my ISPs. For HOME, I route all requests to ISP1. For DMZ, I route all requests to ISP2. For inbound traffic, I NAT all requests from ISP1 to HOME subnet/server (if you need inbound access) and from ISP2 to the DMZ subnet/server (in your case to the IP of the Webserver)