2. depends upon the type of RAIDZ, the ZFS version, and your patience for replacing one disk at a time and waiting for resilvering. Instructions are at http://doc.freenas.org/index.php/Volumes#Replacing_Drives_to_Grow_a_ZFS_Pool. Note that in a RAIDZ1 if one disk fails during the resilver, the pool is lost, so make sure you have a full backup. Which brings us back to why #1 is the safest and most likely the quickest method.