I'm currently running 8.0 release on 32bit Intel hardware with 4 SATA drives in RAIDZ, 2 on MB ports and 2 on a PCI Promise controller. I am planning to build a new system using 8.0.3 when it comes out, on new 64bit AMD hardware with onboard SATA (AMD SB700). Can I save the current configuration and reinstall it on the new hardware, assuming I get the drives installed in the same order as they appear on the existing system? Do I need to do an "export" in addition to a "configuration backup" ?
Yes, you can save/restore your configuration and reinstall it on the new hardware.
Yes, you should export your pool first, before you move everything.
You shouldn't need to worry about the order of the disks, they each have a label/signature that allows ZFS to import them correctly even if they're not in the same order.
You will probably need to do an Auto-Import of your pool on the new hardward because the controller will be different and if you save your config on the old machine before you export your pool, then when you restore your settings the device info could be wrong in the database, ie. ata0 instead of ada0.... THAT will confuse FreeNAS, but your pool will be fine. Just export your pool first, then backup your setttings or do a backup before & after exporting.
Don't stress, everything should go smoothly.