That would be sorta cool, but FreeNAS just loads from a compressed image on the flash drive into RAM, so it would be like having RAID1 with your RAM. All the changes you make from the GUI get written back into a database, and a few other config files/logs get written back to flash, but the point is to NOT write to flash to make it last. So the answer is no, but maybe you could setup a Cron script with rsync and back up the config files somewhere (not your pool).