As far as I know you can't add disks to an existing vdev (ex. RAID-Z).
What you can do is add a new vdev to an existing pool.
For examply. You have created a volume of 3 disks in a RAID-Z configuration and named it "tank".
Now you want to add another 3 disks (also in RAID-Z). To do so you need to perform the exact same steps as the first one and use the same name "tank" for the volume. During the creation freenas will create a new vdev and add it to the existing volume "tank", resulting in a doubling of the available space.
There is 1 remark though: If you add disks to an existing volume, you need to use the same redundancy, because ZFS stripes the vdev's and if 1 vdev (array of 3 disks) is lost, all data of the pool is lost.
EDIT: just realised this is also mentioned in the FAQ (question 2) that 'protosd' created:
FAQ