I´ve done this on a Asrock Board with a Phenom II X3 and Windows 7 to get a quad-core.
If your board has ACC, just try it it out if it works or not, with some CPUs it works but not with all. I´ve tested mine with prime95 during 2 days with no problem so I was sure that it works, if it don´t work you will get a blue-screen or other errors.
If this is your freenas box, I would recommend to disconnect the HDDs first and use an old HDD with windows for example to start some benchmarks or CPU tests to be sure to not lost your data. If it works you will get more CPU cores for your FN box.