I don't know anything about box.com, but I'm fairly certain there's some way to do what you want and also fairly certain you're not the first one that has thought about doing it. :)
A quick peek at their FAQ shows that you can upload stuff with FTP. If I recall correctly, Rsync can move files over FTP, so I'd study up on Rsync and spend some time getting familiar with the FreeNAS manual.
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